The Complexed Triphosphaallyl Radical, Cation, and Anion Family
نویسندگان
چکیده
منابع مشابه
The complexed triphosphaallyl radical, cation, and anion family.
Radically complex: The photolytic reaction of [Cp*P{W(CO)(5)}(2)] (Cp* = C(5)Me(5)) with a diphosphene produces, via a radical intermediate, an air-stable complexed triphosphaallyl radical, in which the unpaired electron is evenly distributed over both terminal P atoms. Oxidation of the radical leads to a triphosphaallyl cation, which is only stable at low temperatures in solution, whereas the ...
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ژورنال
عنوان ژورنال: Angewandte Chemie International Edition
سال: 2009
ISSN: 1433-7851,1521-3773
DOI: 10.1002/anie.200805892